Photopolymerization of acrylate monomer miniemulsions: from fundamentals to implementation in photoreactors
Over the last 40 years, miniemulsion polymerization has resulted in the generation of many polymer colloidal structures, currently unattainable by other heterophase processes. One of its salient features is the virtual lack of monomer transport across the aqueous phase. As a result, the nucleation takes place preferentially in monomer droplets, whi